Toward the Shell Biorefinery: Processing Crustacean Shell Waste Using Hot Water and Carbonic Acid

• Published in: ACS sustainable chemistry & engineering 2019-03, Vol.7 (5), p.5532-5542
• Main Authors: Yang, Huiying, Gözaydın, Gökalp, Nasaruddin, Ricca Rahman, Har, Jie Ren Gerald, Chen, Xi, Wang, Xiaonan, Yan, Ning
• Format: Article
• Language: English
• ISSN: 2168-0485; 2168-0485
• DOI: 10.1021/acssuschemeng.8b06853

Biomass fractionation is a prerequisite for almost any biorefinery process. Yet, a cost-effective and environmentally benign approach to separate biomass feedstock into valuable fractions remain a challenge. Herein we introduce a new fractionation method to extract high value chitin from crustacean shell (e.g., shrimp shell) using hot water for deproteinization and carbonic acid for demineralization (termed as the HOW-CA process). This method features high deproteinization and demineralization efficiencies (>90%), and the whole process is accomplished within hours. The desired final product chitin exhibits a high purity. This work addresses the major problems associated with the current industrial practice including the employment of corrosive reagents, the destructive removal of a useful component, and the generation of a large amount of waste. Economic and life-cycle analyses imply that the HOW-CA process is superior to the conventional method, offering both economic and environmental benefits.