A Novel Pillar-Layered Organic−Inorganic Hybrid Based on Lanthanide Polymer and Polyomolybdate Clusters:  New Opportunity toward the Design and Synthesis of Porous Framework

An unprecedented microporous lanthanum polymolybdate, [{La(H2O)5(dipic)}{La(H2O)(dipic)}]2{Mo8O26}·10H2O (H2dipic = pyridine-2,6-dicarboxylic acid) 1, which is constructed from lanthanum−organic coordination polymer sheets pillared by individual octamolybdate clusters, is reported.

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Bibliographic Details
Published in:Crystal growth & design 2005-01, Vol.5 (1), p.65-67
Main Authors: Lü, Jian, Shen, Enhong, Li, Yangguang, Xiao, Dongrong, Wang, Enbo, Xu, Lin
Format: Article
Language:English
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Summary:An unprecedented microporous lanthanum polymolybdate, [{La(H2O)5(dipic)}{La(H2O)(dipic)}]2{Mo8O26}·10H2O (H2dipic = pyridine-2,6-dicarboxylic acid) 1, which is constructed from lanthanum−organic coordination polymer sheets pillared by individual octamolybdate clusters, is reported.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg049732j