Polynuclear Core-Based Nickel 1,4-Cyclohexanedicarboxylate Coordination Polymers as Temperature-Dependent Hydrothermal Reaction Products

Three nickel 1,4-cyclohexanedicarboxylate (1,4-CDC) coordination polymers, Ni6(OH)6(1,4-CDC)3(H2O)6·2H2O (1), Ni3(OH)2(1,4-CDC)2(H2O)4·4H2O (2), and Ni(1,4-CDC)(H2O)4 (3), have been synthesized from an identical starting mixture as temperature-dependent products. Their characteristic structures and...

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Bibliographic Details
Published in:Crystal growth & design 2006-03, Vol.6 (3), p.664-668
Main Authors: Chen, Jinxi, Ohba, Masaaki, Zhao, Dongyuan, Kaneko, Wakako, Kitagawa, Susumu
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Growth from solutions
Materials science
Methods of crystal growth
physics of crystal growth
Organic compounds
Organometalloidal and organometallic compounds
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:Three nickel 1,4-cyclohexanedicarboxylate (1,4-CDC) coordination polymers, Ni6(OH)6(1,4-CDC)3(H2O)6·2H2O (1), Ni3(OH)2(1,4-CDC)2(H2O)4·4H2O (2), and Ni(1,4-CDC)(H2O)4 (3), have been synthesized from an identical starting mixture as temperature-dependent products. Their characteristic structures and magnetic and sorption behaviors are reported.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg050363g