A Novel Interpenetrating Diamondoid Network from Self-Assembly of N,N′-Di(4-pyridyl)adipoamide and Copper Sulfate: An Unusual 12-Fold, [6 + 6] Mode

The polymeric complex [CuSO4(L)(H2O)2]∞, 1, which was prepared by the reaction of a flexible ligand N,N′-di(4-pyridyl)adipoamide), L, and copper sulfate forms a 12-fold diamondoid network showing an unusual [6 + 6] mode of interpenetration. The L ligands in 1 adopt the AAA trans and GAG trans confor...

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Bibliographic Details
Published in:Crystal growth & design 2008-04, Vol.8 (4), p.1094-1096
Main Authors: Hsu, Yi-Fen, Lin, Chia-Her, Chen, Jhy-Der, Wang, Ju-Chun
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Growth from solutions
Materials science
Methods of crystal growth
physics of crystal growth
Organic compounds
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:The polymeric complex [CuSO4(L)(H2O)2]∞, 1, which was prepared by the reaction of a flexible ligand N,N′-di(4-pyridyl)adipoamide), L, and copper sulfate forms a 12-fold diamondoid network showing an unusual [6 + 6] mode of interpenetration. The L ligands in 1 adopt the AAA trans and GAG trans conformations which also differ in the dihedral angle between the two pyridyl rings.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg701209k