Crystal Water of Cadmium Acetate-Dependent Formation of One-Dimensional Channel Structure Based on 4,4′-bis(1-Imidazolyl)biphenyl

A novel metal-organic framework with one-dimensional channels {[Cd(3)(CH3COO)2(H2O)2] (CH3CN)x(CH3OH)y} (5), based on conformationally restricted linear 4,4′-bis(1-imidazolyl)biphenyl (3) and cadmium acetate dihydrate, has been synthesized. It crystallizes in the triclinic system, space group P1̅ wi...

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Bibliographic Details
Published in:Crystal growth & design 2008-09, Vol.8 (9), p.3134-3136
Main Authors: Zhang, Shiyong, Lan, Jingbo, Mao, Zhihua, Xie, Rugang, You, Jingsong
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Organic compounds
Other materials
Physics
Specific materials
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:A novel metal-organic framework with one-dimensional channels {[Cd(3)(CH3COO)2(H2O)2] (CH3CN)x(CH3OH)y} (5), based on conformationally restricted linear 4,4′-bis(1-imidazolyl)biphenyl (3) and cadmium acetate dihydrate, has been synthesized. It crystallizes in the triclinic system, space group P1̅ with a = 5.6528(11) Å, b = 9.887(3) Å, c = 12.924(3) Å, and Z = 1. The experimental results demonstrate that coordinated crystal water molecules may play a key role in the formation of the metal-organic frameworks.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg800038j