Supramolecular Aggregation of Pd(II) Monohelicates Directed by Discrete (H2O)8 Clusters in a 1,4-Diaxially Substituted Hexameric Chairlike Conformation

We report the first structural evidence in the solid state of discrete water octamers with a 1,4-diaxially substituted hexameric chairlike conformation. These units were found to act as supramolecular glue in the aggregation of Pd(II) monohelicates to give a three-dimensional network through hydroge...

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Bibliographic Details
Published in:Crystal growth & design 2008-07, Vol.8 (7), p.2083-2086
Main Authors: Vázquez López, Miguel, Zaragoza, Guillermo, Otero, Marta, Pedrido, Rosa, Rama, Gustavo, Bermejo, Manuel R.
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Organic compounds
Other materials
Physics
Specific materials
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:We report the first structural evidence in the solid state of discrete water octamers with a 1,4-diaxially substituted hexameric chairlike conformation. These units were found to act as supramolecular glue in the aggregation of Pd(II) monohelicates to give a three-dimensional network through hydrogen-bonding.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg800308s