Supramolecular Aggregation of Pd(II) Monohelicates Directed by Discrete (H2O)8 Clusters in a 1,4-Diaxially Substituted Hexameric Chairlike Conformation

We report the first structural evidence in the solid state of discrete water octamers with a 1,4-diaxially substituted hexameric chairlike conformation. These units were found to act as supramolecular glue in the aggregation of Pd(II) monohelicates to give a three-dimensional network through hydroge...

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Published in:Crystal growth & design 2008-07, Vol.8 (7), p.2083-2086
Main Authors: Vázquez López, Miguel, Zaragoza, Guillermo, Otero, Marta, Pedrido, Rosa, Rama, Gustavo, Bermejo, Manuel R.
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Organic compounds
Other materials
Physics
Specific materials
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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cited_by cdi_FETCH-LOGICAL-a204t-c64453fc535a884ee83458cab1aa5a9e5110d2cff7ed3416201daeb2d45835923
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container_issue 7
container_start_page 2083
container_title Crystal growth & design
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creator Vázquez López, Miguel
Zaragoza, Guillermo
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description We report the first structural evidence in the solid state of discrete water octamers with a 1,4-diaxially substituted hexameric chairlike conformation. These units were found to act as supramolecular glue in the aggregation of Pd(II) monohelicates to give a three-dimensional network through hydrogen-bonding.
doi_str_mv 10.1021/cg800308s
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Organic compounds
Other materials
Physics
Specific materials
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
title Supramolecular Aggregation of Pd(II) Monohelicates Directed by Discrete (H2O)8 Clusters in a 1,4-Diaxially Substituted Hexameric Chairlike Conformation
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