Preparation of Smaller Nine- and Ten-Vertex Monocarbaborane Cages by the Selective Dismantling of Twelve-Vertex Dicarbaboranes via the [nido-7,9-C2B10H13]- Anion. Synthesis of the Monocarbaborane Base Adducts endo-9-Me-8-(NMe3)-arachno-6-CB9H12, 9-Me-8-L-nido-6-CB9H10 (L = NMe3, OH-), and exo-6-L-arachno-4-CB8H12 (L = SMe2, NMe3, Urotropine, Pyridine, Quinoline, MeCN, PPh3, MeNC)

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Bibliographic Details
Published in:Inorganic chemistry 1994-06, Vol.33 (13), p.2994-3002
Main Authors: Plesek, Jaromir, Stibr, Bohumil, Fontaine, Xavier L. R, Jelinek, Tomas, Thornton-Pett, Mark, Hermanek, Stanislav, Kennedy, John D
Format: Article
Language:English
Subjects:
B derivatives
Chemistry
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Organic chemistry
Organic compounds
Organometalloidal and organometallic compounds
Physics
Preparations and properties
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic00091a045