Development of a Series of P(CH2NCHR)3 and Trisubstituted 1,3,5-Triaza-7-phosphaadamantane Ligands

The synthesis and structure of a series of novel phosphine ligands derived from the condensation of P(CH2NH2) with aldehydes are described. Depending on the reaction conditions, either substituted tris(iminomethyl)phosphine, P(CH2NCHR)3, or 1,3,5-triaza-7-phosphaadamantane structures substituted at...

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Bibliographic Details
Published in:Inorganic chemistry 2007-12, Vol.46 (26), p.10962-10964
Main Authors: Huang, Rongcai, Frost, Brian J
Format: Article
Language:English
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Summary:The synthesis and structure of a series of novel phosphine ligands derived from the condensation of P(CH2NH2) with aldehydes are described. Depending on the reaction conditions, either substituted tris(iminomethyl)phosphine, P(CH2NCHR)3, or 1,3,5-triaza-7-phosphaadamantane structures substituted at the “lower rim”, PTAR3, are obtained.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic701864g