Interaction of Carbon Dioxide with [IrH2{(tBu2)PCH2CH2CHCH2CH2P(tBu2)}]

The pincer ligand dihydride complex interacts with carbon dioxide to give an isolable bicarbonate derivative and a metal hydride carbonyl compound. An intermediate metallo−formate complex can be detected by NMR spectroscopy. The reaction described is a reverse water gas shift process, CO2 + H2 ⇌ CO...

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Published in:Inorganic chemistry 1999-06, Vol.38 (13), p.3223-3227
Main Authors: McLoughlin, Margaret A, Keder, Nancy L, Harrison, William T. A, Flesher, Robert J, Mayer, Hermann A, Kaska, William C
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Language:English
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cited_by cdi_FETCH-LOGICAL-a295t-107cc989cf0243e6e6dbafbaed1d52153a8794235bb74cdbb6f4fc5cdece95483
cites cdi_FETCH-LOGICAL-a295t-107cc989cf0243e6e6dbafbaed1d52153a8794235bb74cdbb6f4fc5cdece95483
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description The pincer ligand dihydride complex interacts with carbon dioxide to give an isolable bicarbonate derivative and a metal hydride carbonyl compound. An intermediate metallo−formate complex can be detected by NMR spectroscopy. The reaction described is a reverse water gas shift process, CO2 + H2 ⇌ CO + H2O.
doi_str_mv 10.1021/ic980722f
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title Interaction of Carbon Dioxide with [IrH2{(tBu2)PCH2CH2CHCH2CH2P(tBu2)}]
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