Strategies for the Immobilization of Homogeneous Catalysts and Their Use in the Synthesis of Carbamates

Different methods of immobilization of N,N′-bis(salicylidene)ethylenediaminocobalt(II), [Co(salen)] complex, using K10 montmorillonite and silica have been used. These supported catalysts are active in the oxidative carbonylation of aniline using NaI as a promoter. The principal products obtained ar...

Full description

Saved in:
Bibliographic Details
Published in:Industrial & engineering chemistry research 2008-11, Vol.47 (21), p.8032-8036
Main Authors: Orejón, Aránzazu, Masdeu-Bultó, Anna M, Salagre, Pilar, Castillón, Sergio, Claver, Carmen, Padilla, Ana, Almena, Beatriz, Serrano, Francisco Luis
Format: Article
Language:English
Subjects:
Applied sciences
Catalysis
Catalytic reactions
Chemical engineering
Chemistry
Exact sciences and technology
General and physical chemistry
Kinetics, Catalysis, and Reaction Engineering
Reactors
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Different methods of immobilization of N,N′-bis(salicylidene)ethylenediaminocobalt(II), [Co(salen)] complex, using K10 montmorillonite and silica have been used. These supported catalysts are active in the oxidative carbonylation of aniline using NaI as a promoter. The principal products obtained are N,N′-diphenylurea and 1-butyl-N-phenylcarbamate.
ISSN:0888-5885
1520-5045
DOI:10.1021/ie8002599