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Improved Antifouling Property of PES Ultrafiltration Membranes Using Additive of Silica−PVP Nanocomposite

To improve the surface coverage of polyvinylpyrrolidone (PVP) on membrane surfaces and further enhance the antifouling property, a silica−PVP nanocomposite was synthesized and used as a novel hydrophilic additive to modify polyethersulfone (PES) membranes. Transmission electron microscopy (TEM) obse...

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Bibliographic Details
Published in:Industrial & engineering chemistry research 2010-01, Vol.49 (2), p.790-796
Main Authors: Sun, Mengping, Su, Yanlei, Mu, Chunxia, Jiang, Zhongyi
Format: Article
Language:English
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Summary:To improve the surface coverage of polyvinylpyrrolidone (PVP) on membrane surfaces and further enhance the antifouling property, a silica−PVP nanocomposite was synthesized and used as a novel hydrophilic additive to modify polyethersulfone (PES) membranes. Transmission electron microscopy (TEM) observation showed that PES membranes, using additives of PVP and silica−PVP nanocomposites, have similar asymmetric structures. X-ray photoelectron spectroscopy (XPS) measurement indicated that the near-surface coverage of PVP for PES membrane with a silica−PVP nanocomposite additive is greater than that with a PVP additive. Protein ultrafiltration experiment also showed that the antifouling ability of PES membrane with a silica-PVP nanocomposite additive is stronger than that with a PVP additive. The hydrophilic modification with a silica−PVP nanocomposite is an appropriate method for improved antifouling property of PES ultrafiltration membranes.
ISSN:0888-5885
1520-5045
DOI:10.1021/ie900560e