A Cubic, 12-Connected, Microporous Metal−Organometallic Phosphate Framework Sustained by Truncated Tetrahedral Nodes

A rare example of a microporous metal−organic phosphate, [Co12(L)6(μ3-PO4)4(μ3-F)4(μ-H2O)6][NO3]2 (1), is synthesized by the reaction of a [(η5-C5H5)FeII]+-functionalized terephthalate ligand with Co(NO3)2·6H2O and phosphate and fluoride ions generated from the in situ hydrolysis of hexafluorophosph...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2011-02, Vol.133 (6), p.1634-1637
Main Authors: Kumalah Robinson, Sayon A., Mempin, Marion-Vincent L., Cairns, Amy J., Holman, K. Travis
Format: Article
Language:English
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Summary:A rare example of a microporous metal−organic phosphate, [Co12(L)6(μ3-PO4)4(μ3-F)4(μ-H2O)6][NO3]2 (1), is synthesized by the reaction of a [(η5-C5H5)FeII]+-functionalized terephthalate ligand with Co(NO3)2·6H2O and phosphate and fluoride ions generated from the in situ hydrolysis of hexafluorophosphate. 1 is a cubic, 12-connected, face-centered cubic framework sustained by the linear connection of unprecedented, dodecanuclear truncated tetrahedral coordination clusters.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja108894a