Solubility of Seven Nonpolar Organic Solvents in Four Polymers Using the Piezoelectric−Quartz Sorption Method

Solubility of octane, cyclopentane, cyclohexane, benzene, toluene, ethylbenzene and p-xylene in cis-1,4-polyisoprene, polyisobutylene, poly(n-butyl methacrylate), and poly(vinyl acetate) were measured by the piezoelectric quartz crystal microbalance method at four temperatures (293.2, 313.2, 333.2,...

Full description

Saved in:
Bibliographic Details
Published in:Journal of chemical and engineering data 2002-05, Vol.47 (3), p.518-524
Main Authors: Wibawa, Gede, Takahashi, Masaki, Sato, Yoshiyuki, Takishima, Shigeki, Masuoka, Hirokatsu
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Solubility
Solutions
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Solubility of octane, cyclopentane, cyclohexane, benzene, toluene, ethylbenzene and p-xylene in cis-1,4-polyisoprene, polyisobutylene, poly(n-butyl methacrylate), and poly(vinyl acetate) were measured by the piezoelectric quartz crystal microbalance method at four temperatures (293.2, 313.2, 333.2, and 353.2) K. In this work, four quartz crystals were installed in an equilibrium cell, which enables multiple solubility measurements. Estimated uncertainties of measured variables were ±0.05 K for temperature, ±0.009 for activity, and ±0.002 for mass fraction. The accuracy of the method was confirmed by comparison with literature data. The activities obtained were correlated by the UNIQUAC equation with an overall AAD of 4.1%.
ISSN:0021-9568
1520-5134
DOI:10.1021/je010310c