Measurement and Prediction of Excess Molar Enthalpies and Excess Molar Volumes of the Ternary System 1,3-Dichlorobenzene + Benzene + Hexane at 298.15 K

Experimental excess molar enthalpies and excess molar volumes for the ternary system {x 1 1,3-dichlorobenzene + x 2 benzene + (1− x 1 − x 2) hexane} have been determined at the temperature of 298.15 K and atmospheric pressure. Values of excess molar enthalpies were measured using a Calvet microcalor...

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Bibliographic Details
Published in:Journal of chemical and engineering data 2004-07, Vol.49 (4), p.928-932
Main Authors: Mato, Marta M, Jímenez, Eulogio, Legido, José Luis, Paz Andrade, María Inmaculada
Format: Article
Language:English
Subjects:
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
Mixtures
Thermodynamic properties
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Summary:Experimental excess molar enthalpies and excess molar volumes for the ternary system {x 1 1,3-dichlorobenzene + x 2 benzene + (1− x 1 − x 2) hexane} have been determined at the temperature of 298.15 K and atmospheric pressure. Values of excess molar enthalpies were measured using a Calvet microcalorimeter, and excess molar volumes were determined from the densities of the pure liquids and mixtures, using a vibrating-tube densimeter. Several empirical expressions for estimating ternary properties from experimental binary results were applied.
ISSN:0021-9568
1520-5134
DOI:10.1021/je034237x