Vapor−Liquid Equilibrium of Binary Mixtures Containing Ethyl Acetate + 2-Methyl-1-propanol and Ethyl Acetate + 2-Methyl-1-butanol at 101.3 kPa

Isobaric vapor−liquid equilibria (VLE) data at 101.3 kPa were reported for the binary mixtures ethyl acetate + 2-methyl-1-propanol and ethyl acetate + 2-methyl-1-butanol. VLE experimental data were tested for thermodynamic consistency by means of a modified Dechema test and were demonstrated to be c...

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Bibliographic Details
Published in:Journal of chemical and engineering data 2006-03, Vol.51 (2), p.595-598
Main Authors: Resa, José M, Goenaga, José M, Lanz, Juan, Iglesias, Miguel
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Liquid-vapor equilibria
Phase equilibria
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Summary:Isobaric vapor−liquid equilibria (VLE) data at 101.3 kPa were reported for the binary mixtures ethyl acetate + 2-methyl-1-propanol and ethyl acetate + 2-methyl-1-butanol. VLE experimental data were tested for thermodynamic consistency by means of a modified Dechema test and were demonstrated to be consistent. The activity coefficients were correlated with the Margules, van Laar, UNIQUAC, NRTL, and Wilson equations. The ASOG model also was used for prediction.
ISSN:0021-9568
1520-5134
DOI:10.1021/je050420+