Water Activity in Aqueous Amino Acid Solutions Containing Ammonium Sulfate at 298.2 K

• Published in: Journal of chemical and engineering data 2014-06, Vol.59 (6), p.1802-1807
• Main Authors: Vilarinho, Mário F, Fernandes, Isa C, Pinho, Simão P
• Format: Article
• Language: English
• ISSN: 0021-9568; 1520-5134
• DOI: 10.1021/je401034k

Water activity in aqueous solutions of dl-alanine, glycine, or l-serine, with ammonium sulfate, molality ranging from 0.5 to 5.0, have been measured at 298.2 K. The new experimental data was correlated using three different theoretical schemes such as Zdanovskii–-Stokes–Robinson, its extension, or the Clegg–Seinfeld–Brimblecombe approach, with global average absolute deviations in the calculation of the osmotic coefficient of 3.46 %, 0.93 % and 1.95 %, respectively. The extended Zdanovskii–Stokes–Robinson method also enabled the prediction of unsymmetric molal activity coefficients of the electrolyte, in fair agreement with the experimental values found from literature measured by an electrochemical method. It is evidenced the usefulness of the experimental ternary data measured to extend the capabilities of thermodynamic models to higher salt and amino acid concentrations.