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Activity Coefficients at Infinite Dilution of Alkanols in the Ionic Liquids 1-Butyl-3-methylimidazolium Hexafluorophosphate, 1-Butyl-3-methylimidazolium Methyl Sulfate, and 1-Hexyl-3-methylimidazolium Bis(trifluoromethylsulfonyl) Amide Using the Dilutor Technique

Activity coefficients at infinite dilution were measured for eight alkanols (methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2-propanol) in the three ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), 1-butyl-3-methylimidaz...

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Bibliographic Details
Published in:Journal of chemical and engineering data 2008-09, Vol.53 (9), p.2154-2162
Main Authors: Dobryakov, Yuri G, Tuma, Dirk, Maurer, Gerd
Format: Article
Language:English
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Summary:Activity coefficients at infinite dilution were measured for eight alkanols (methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2-propanol) in the three ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), 1-butyl-3-methylimidazolium methyl sulfate ([bmim][CH3SO4]), and 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) amide ([hmim][Tf2N]) between (293.15 and 353.15) K using the dilutor technique. The results are presented and, as far as possible, compared with literature data.
ISSN:0021-9568
1520-5134
DOI:10.1021/je800355e