Experimental Determination and Modeling of Methane Hydrates in Mixtures of Acetone and Water

In this article, experimental data on methane hydrate formation in mixtures of water and acetone are presented. For eight different acetone−water mixtures, the phase transition hydrate + liquid + vapor → liquid + vapor (HLV → LV) was determined in the pressure range 2.50 < p/MPa < 11.25. In ad...

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Published in:Journal of chemical and engineering data 1997-09, Vol.42 (5), p.948-950
Main Authors: Mainusch, S, Peters, C. J, de Swaan Arons, J, Javanmardi, J, Moshfeghian, M
Format: Article
Language:English
Subjects:
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
Thermodynamic properties
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description In this article, experimental data on methane hydrate formation in mixtures of water and acetone are presented. For eight different acetone−water mixtures, the phase transition hydrate + liquid + vapor → liquid + vapor (HLV → LV) was determined in the pressure range 2.50 < p/MPa < 11.25. In addition, the experimental data obtained were described by a model that takes into account the variation of the enthalpy of hydrate formation as a function of pressure and acetone concentration. The average absolute temperature difference in the representation of the hydrate formation temperatures of methane in the presence of acetone is less than 0.32 K.
doi_str_mv 10.1021/je970039s
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
Thermodynamic properties
title Experimental Determination and Modeling of Methane Hydrates in Mixtures of Acetone and Water
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