Synthesis of a New Water-Soluble C 2-Symmetric Chiral Diamine:  Preliminary Investigation of Its Catalytic Properties for Asymmetric Hydrogenation under Biphasic Conditions

A water-soluble version of N,N ‘-dimethyl-1,2-diphenylethane-1,2-diamine was prepared by introduction of phosphonic acid moieties on the para position of the aromatic rings. Preliminary investigation of the catalytic properties of the iridium complex of this ligand under biphasic conditions showed t...

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Published in:Journal of organic chemistry 2002-11, Vol.67 (23), p.8191-8196
Main Authors: Maillet, Céline, Praveen, Thoniyot, Janvier, Pascal, Minguet, Sébastien, Evain, Michel, Saluzzo, Christine, Tommasino, M. Lorraine, Bujoli, Bruno
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cited_by cdi_FETCH-LOGICAL-a189t-5462d719c55b9fb6d3244ca4a2e3f8fd13c408adda1377b04ffc4b139a8990403
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container_end_page 8196
container_issue 23
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container_title Journal of organic chemistry
container_volume 67
creator Maillet, Céline
Praveen, Thoniyot
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description A water-soluble version of N,N ‘-dimethyl-1,2-diphenylethane-1,2-diamine was prepared by introduction of phosphonic acid moieties on the para position of the aromatic rings. Preliminary investigation of the catalytic properties of the iridium complex of this ligand under biphasic conditions showed that this system compared well with the homogeneous counterpart for the asymmetric hydrogenation of ketones but with noticeably higher reaction rates for the biphasic system.
doi_str_mv 10.1021/jo020506v
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title Synthesis of a New Water-Soluble C 2-Symmetric Chiral Diamine:  Preliminary Investigation of Its Catalytic Properties for Asymmetric Hydrogenation under Biphasic Conditions
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