Hydrogenation of the Carbonyl Group in α-Ketoesters and α-Ketoamides Catalyzed by Ruthenium Clay

Ruthenium clay, prepared by reaction of RuCl3·H2O with the 3-phosphinopropyl ligand anchored on Fluka K10 montmorillonite, is an effective catalyst for the reduction of the α-carbonyl group of α-ketoesters and α-ketoamides (50−89% yield).

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Bibliographic Details
Published in:Journal of organic chemistry 1998-12, Vol.63 (25), p.9425-9426
Main Authors: Aldea, Raluca, Alper, Howard
Format: Article
Language:English
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Summary:Ruthenium clay, prepared by reaction of RuCl3·H2O with the 3-phosphinopropyl ligand anchored on Fluka K10 montmorillonite, is an effective catalyst for the reduction of the α-carbonyl group of α-ketoesters and α-ketoamides (50−89% yield).
ISSN:0022-3263
1520-6904
DOI:10.1021/jo981447h