Methane Carbonylation with CO on Sulfated Zirconia:  Evidence from Solid-State NMR for the Selective Formation of Acetic Acid

Using 13C and 1H solid-state NMR it has been shown, that methane can be carbonylated with carbon monoxide to give acetic acid on solid acid catalyst, sulfated zirconia. The carbonylation occurs at 473−573 K with high selectivity and essential conversion. The reaction proceeds both in the absence and...

Full description

Saved in:
Bibliographic Details
Published in:Journal of physical chemistry. C 2007-07, Vol.111 (28), p.10624-10629
Main Authors: Luzgin, Mikhail V, Rogov, Vladimir A, Kotsarenko, Nina S, Shmachkova, Vera P, Stepanov, Alexander G
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a297t-68c0b7407c2676c10482261363fa69702305d4d7f2566dbed04958de686c5f4e3
cites cdi_FETCH-LOGICAL-a297t-68c0b7407c2676c10482261363fa69702305d4d7f2566dbed04958de686c5f4e3
container_end_page 10629
container_issue 28
container_start_page 10624
container_title Journal of physical chemistry. C
container_volume 111
creator Luzgin, Mikhail V
Rogov, Vladimir A
Kotsarenko, Nina S
Shmachkova, Vera P
Stepanov, Alexander G
description Using 13C and 1H solid-state NMR it has been shown, that methane can be carbonylated with carbon monoxide to give acetic acid on solid acid catalyst, sulfated zirconia. The carbonylation occurs at 473−573 K with high selectivity and essential conversion. The reaction proceeds both in the absence and in the presence of molecular oxygen. In the presence of oxygen, the catalyst can be used for the carbonylation of further portion of methane without reactivation in air. The mechanism of the reaction is discussed. The reaction observed opens up new possibilities of using sulfated zirconia-based solid catalysts for the synthesis of acetic acid from methane and carbon monoxide.
doi_str_mv 10.1021/jp0728757
format article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_jp0728757</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>a350499656</sourcerecordid><originalsourceid>FETCH-LOGICAL-a297t-68c0b7407c2676c10482261363fa69702305d4d7f2566dbed04958de686c5f4e3</originalsourceid><addsrcrecordid>eNptkLtOwzAARSMEEqUw8AdeGBgCjh3bKVsVUYroA0gREovl-qG6pHHluIVOsPKbfAlBRZ2Y7h2OjnRvFJ0m8CKBKLmcLyFDGSNsL2olHYxilhKyv-spO4yO6noOIcEwwa3oY6jDTFQa5MJPXbUpRbCuAm82zEA-Bk0tVqURQSvwYr10lRVX359f4Hptla6kBsa7BShcaVVchIYDo-EjMM6DMNOg0KWWwa416Dm_2KqdAV2pg5VNWHUcHRhR1vrkL9vRU-96kvfjwfjmNu8OYoE6LMQ0k3DKUsgkoozKBKYZQjTBFBtBOwwiDIlKFTOIUKqmWsG0QzKlaUYlManG7eh865Xe1bXXhi-9XQi_4Qnkv8_x3XMNG29ZWwf9vgOFf-WUYUb45L7gd6OH4hn3Kc8a_mzLC1nzuVv5qlnyj_cHxgF77A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Methane Carbonylation with CO on Sulfated Zirconia:  Evidence from Solid-State NMR for the Selective Formation of Acetic Acid</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Luzgin, Mikhail V ; Rogov, Vladimir A ; Kotsarenko, Nina S ; Shmachkova, Vera P ; Stepanov, Alexander G</creator><creatorcontrib>Luzgin, Mikhail V ; Rogov, Vladimir A ; Kotsarenko, Nina S ; Shmachkova, Vera P ; Stepanov, Alexander G</creatorcontrib><description>Using 13C and 1H solid-state NMR it has been shown, that methane can be carbonylated with carbon monoxide to give acetic acid on solid acid catalyst, sulfated zirconia. The carbonylation occurs at 473−573 K with high selectivity and essential conversion. The reaction proceeds both in the absence and in the presence of molecular oxygen. In the presence of oxygen, the catalyst can be used for the carbonylation of further portion of methane without reactivation in air. The mechanism of the reaction is discussed. The reaction observed opens up new possibilities of using sulfated zirconia-based solid catalysts for the synthesis of acetic acid from methane and carbon monoxide.</description><identifier>ISSN: 1932-7447</identifier><identifier>EISSN: 1932-7455</identifier><identifier>DOI: 10.1021/jp0728757</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Journal of physical chemistry. C, 2007-07, Vol.111 (28), p.10624-10629</ispartof><rights>Copyright © 2007 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a297t-68c0b7407c2676c10482261363fa69702305d4d7f2566dbed04958de686c5f4e3</citedby><cites>FETCH-LOGICAL-a297t-68c0b7407c2676c10482261363fa69702305d4d7f2566dbed04958de686c5f4e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Luzgin, Mikhail V</creatorcontrib><creatorcontrib>Rogov, Vladimir A</creatorcontrib><creatorcontrib>Kotsarenko, Nina S</creatorcontrib><creatorcontrib>Shmachkova, Vera P</creatorcontrib><creatorcontrib>Stepanov, Alexander G</creatorcontrib><title>Methane Carbonylation with CO on Sulfated Zirconia:  Evidence from Solid-State NMR for the Selective Formation of Acetic Acid</title><title>Journal of physical chemistry. C</title><addtitle>J. Phys. Chem. C</addtitle><description>Using 13C and 1H solid-state NMR it has been shown, that methane can be carbonylated with carbon monoxide to give acetic acid on solid acid catalyst, sulfated zirconia. The carbonylation occurs at 473−573 K with high selectivity and essential conversion. The reaction proceeds both in the absence and in the presence of molecular oxygen. In the presence of oxygen, the catalyst can be used for the carbonylation of further portion of methane without reactivation in air. The mechanism of the reaction is discussed. The reaction observed opens up new possibilities of using sulfated zirconia-based solid catalysts for the synthesis of acetic acid from methane and carbon monoxide.</description><issn>1932-7447</issn><issn>1932-7455</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNptkLtOwzAARSMEEqUw8AdeGBgCjh3bKVsVUYroA0gREovl-qG6pHHluIVOsPKbfAlBRZ2Y7h2OjnRvFJ0m8CKBKLmcLyFDGSNsL2olHYxilhKyv-spO4yO6noOIcEwwa3oY6jDTFQa5MJPXbUpRbCuAm82zEA-Bk0tVqURQSvwYr10lRVX359f4Hptla6kBsa7BShcaVVchIYDo-EjMM6DMNOg0KWWwa416Dm_2KqdAV2pg5VNWHUcHRhR1vrkL9vRU-96kvfjwfjmNu8OYoE6LMQ0k3DKUsgkoozKBKYZQjTBFBtBOwwiDIlKFTOIUKqmWsG0QzKlaUYlManG7eh865Xe1bXXhi-9XQi_4Qnkv8_x3XMNG29ZWwf9vgOFf-WUYUb45L7gd6OH4hn3Kc8a_mzLC1nzuVv5qlnyj_cHxgF77A</recordid><startdate>20070719</startdate><enddate>20070719</enddate><creator>Luzgin, Mikhail V</creator><creator>Rogov, Vladimir A</creator><creator>Kotsarenko, Nina S</creator><creator>Shmachkova, Vera P</creator><creator>Stepanov, Alexander G</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20070719</creationdate><title>Methane Carbonylation with CO on Sulfated Zirconia:  Evidence from Solid-State NMR for the Selective Formation of Acetic Acid</title><author>Luzgin, Mikhail V ; Rogov, Vladimir A ; Kotsarenko, Nina S ; Shmachkova, Vera P ; Stepanov, Alexander G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a297t-68c0b7407c2676c10482261363fa69702305d4d7f2566dbed04958de686c5f4e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Luzgin, Mikhail V</creatorcontrib><creatorcontrib>Rogov, Vladimir A</creatorcontrib><creatorcontrib>Kotsarenko, Nina S</creatorcontrib><creatorcontrib>Shmachkova, Vera P</creatorcontrib><creatorcontrib>Stepanov, Alexander G</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Journal of physical chemistry. C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Luzgin, Mikhail V</au><au>Rogov, Vladimir A</au><au>Kotsarenko, Nina S</au><au>Shmachkova, Vera P</au><au>Stepanov, Alexander G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Methane Carbonylation with CO on Sulfated Zirconia:  Evidence from Solid-State NMR for the Selective Formation of Acetic Acid</atitle><jtitle>Journal of physical chemistry. C</jtitle><addtitle>J. Phys. Chem. C</addtitle><date>2007-07-19</date><risdate>2007</risdate><volume>111</volume><issue>28</issue><spage>10624</spage><epage>10629</epage><pages>10624-10629</pages><issn>1932-7447</issn><eissn>1932-7455</eissn><abstract>Using 13C and 1H solid-state NMR it has been shown, that methane can be carbonylated with carbon monoxide to give acetic acid on solid acid catalyst, sulfated zirconia. The carbonylation occurs at 473−573 K with high selectivity and essential conversion. The reaction proceeds both in the absence and in the presence of molecular oxygen. In the presence of oxygen, the catalyst can be used for the carbonylation of further portion of methane without reactivation in air. The mechanism of the reaction is discussed. The reaction observed opens up new possibilities of using sulfated zirconia-based solid catalysts for the synthesis of acetic acid from methane and carbon monoxide.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp0728757</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1932-7447
ispartof Journal of physical chemistry. C, 2007-07, Vol.111 (28), p.10624-10629
issn 1932-7447
1932-7455
language eng
recordid cdi_crossref_primary_10_1021_jp0728757
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
title Methane Carbonylation with CO on Sulfated Zirconia:  Evidence from Solid-State NMR for the Selective Formation of Acetic Acid
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-21T17%3A22%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Methane%20Carbonylation%20with%20CO%20on%20Sulfated%20Zirconia:%E2%80%89%20Evidence%20from%20Solid-State%20NMR%20for%20the%20Selective%20Formation%20of%20Acetic%20Acid&rft.jtitle=Journal%20of%20physical%20chemistry.%20C&rft.au=Luzgin,%20Mikhail%20V&rft.date=2007-07-19&rft.volume=111&rft.issue=28&rft.spage=10624&rft.epage=10629&rft.pages=10624-10629&rft.issn=1932-7447&rft.eissn=1932-7455&rft_id=info:doi/10.1021/jp0728757&rft_dat=%3Cacs_cross%3Ea350499656%3C/acs_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a297t-68c0b7407c2676c10482261363fa69702305d4d7f2566dbed04958de686c5f4e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true