Relaxation Processes and Structural Changes in Li- and Na-Doped Fulleranes for Hydrogen Storage

• Published in: Journal of physical chemistry. C 2012-08, Vol.116 (31), p.16365-16370
• Main Authors: Paolone, A, Vico, F, Teocoli, F, Sanna, S, Palumbo, O, Cantelli, R, Knight, D. A, Teprovich, J. A, Zidan, R
• Format: Article
• Language: English
• Subjects: Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Fullerenes and related materials; diamonds, graphite; Materials science; Mechanical and acoustical properties of condensed matter; Mechanical properties of nanoscale materials; Physics; Specific materials
• ISSN: 1932-7447; 1932-7455
• DOI: 10.1021/jp304552r

The anelastic spectra of Li6C60H x and Na6C60H x have been measured for the first time. The spectra of composite materials obtained by mixing of LiH and NaH with C60 in a solvent still show the structural phase transition around 260 K and preserve the buckyball dynamics of pure fullerenes but do not show the spectral features of the hydrides. This observation suggests that the composite materials are homogeneous samples in which the hydrides are finely dispersed in the fullerene crystal and therefore lose their features. However, after dehydrogenation and after rehydrogenation both the phase transition and the dynamic process are completely suppressed, indicating a deep modification of the lattice structure, possibly due to polymerization. The present study indicates that Li6C60H x and Na6C60H x are homogeneous materials and cannot be considered as constituted by bulk C60H n and Li(Na)H x , as suggested by a previous study.