Methane Decomposition Using Metal-Assisted Nanosecond Laser-Induced Plasma at Atmospheric Pressure

Methane decomposition has been extensively investigated using a Q-switched Nd:YAG laser, focused on the metal catalysts including Ni, Fe, Pd, and Cu within the controlled chamber to verify the effect of catalyst, plasma properties, and yield and selectivity of the products. Fourier transform IR spec...

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Bibliographic Details
Published in:Journal of physical chemistry. C 2014-12, Vol.118 (51), p.29822-29835
Main Authors: Ghorbani, Z, Parvin, P, Reyhani, A, Mortazavi, S. Z, Moosakhani, A, Maleki, M, Kiani, S
Format: Article
Language:English
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Summary:Methane decomposition has been extensively investigated using a Q-switched Nd:YAG laser, focused on the metal catalysts including Ni, Fe, Pd, and Cu within the controlled chamber to verify the effect of catalyst, plasma properties, and yield and selectivity of the products. Fourier transform IR spectroscopy (FTIR) and gas chromatography (GC) are employed to support the characterization of the components. This indicates that methane is strongly decomposed within the metal-assisted laser-induced plasma, leading to the subsequent recombination and the production of heavier hydrocarbons. The dominant species, including propane, ethane, and ethylene, have been identified examining different metallic catalysts. The dissociation rate, conversion ratio, selectivity, and yield of products are strongly dependent on the metal target and plasma characteristics.
ISSN:1932-7447
1932-7455
DOI:10.1021/jp508634d