Position and Orientation Control of a Photo- and Electrochromic Dithienylethene Using a Tripodal Anchor on Gold Surfaces

A tripodal system for anchoring photochromic dithienylethenes on gold surfaces is reported. The self-assembled monolayers of a tripod-functionalized dithienylethene were characterized by cyclic voltammetry, surface-enhanced Raman spectroscopy (SERS), and X-ray photoelectron spectroscopy (XPS). These...

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Bibliographic Details
Published in:Journal of physical chemistry. C 2015-02, Vol.119 (7), p.3648-3657
Main Authors: Pijper, Thomas C, Ivashenko, Oleksii, Walko, Martin, Rudolf, Petra, Browne, Wesley R, Feringa, Ben L
Format: Article
Language:English
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Summary:A tripodal system for anchoring photochromic dithienylethenes on gold surfaces is reported. The self-assembled monolayers of a tripod-functionalized dithienylethene were characterized by cyclic voltammetry, surface-enhanced Raman spectroscopy (SERS), and X-ray photoelectron spectroscopy (XPS). These data are compared with solution studies, solid state Raman spectroscopy, and density functional theory (DFT) calculations. We show that the tripod-functionalized dithienylethene forms stable monolayers on gold in which all three legs of the tripod are adsorbed via the thiol units, thus providing a fixed position and orientation of the dithienylethene moiety with respect to the surface. Importantly, immobilization in this way allows for retention of both the photochemical and electrochemical functionality of the dithienylethene unit and reduces photochemical fatigue observed in solution.
ISSN:1932-7447
1932-7455
DOI:10.1021/jp512424d