Nonequilibrium Generalization of Chemical Potential of Flowing Fluids

The contribution of a shear viscous pressure to the chemical potential of the components of a fluid mixture is considered. It is used to study the influence of the shear on the phase diagram (coexistence line, spinodal line, ...) of a polymer solution and on the shear-induced degradation effects.

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Bibliographic Details
Published in:The journal of physical chemistry. B 1998-07, Vol.102 (27), p.5335-5340
Main Authors: Criado-Sancho, M, Jou, D, Casas-Vázquez, J
Format: Article
Language:English
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Summary:The contribution of a shear viscous pressure to the chemical potential of the components of a fluid mixture is considered. It is used to study the influence of the shear on the phase diagram (coexistence line, spinodal line, ...) of a polymer solution and on the shear-induced degradation effects.
ISSN:1520-6106
1520-5207
DOI:10.1021/jp9803790