Droplet Spreading:  Partial Wetting Regime Revisited

We study the time evolution of a sessile liquid droplet, which is initially put onto a solid surface in a nonequilibrium configuration and then evolves towards its equilibrium shape. We adapt here the standard approach to the dynamics of mechanical dissipative systems, in which the driving force, i....

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Bibliographic Details
Published in:Langmuir 1999-03, Vol.15 (6), p.2209-2216
Main Authors: de Ruijter, M. J, De Coninck, J, Oshanin, G
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
General, apparatus
Surface physical chemistry
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Summary:We study the time evolution of a sessile liquid droplet, which is initially put onto a solid surface in a nonequilibrium configuration and then evolves towards its equilibrium shape. We adapt here the standard approach to the dynamics of mechanical dissipative systems, in which the driving force, i.e., the gradient of the system's Lagrangian function, is balanced against the rate of the dissipation function. In our case, the driving force is the loss of the droplet's free energy due to the increase of its base radius, whereas the dissipation occurs because of viscous flows in the core of the droplet and frictional processes in the vicinity of the advancing contact line, associated with attachment of fluid particles to solid. Within this approach, we derive closed-form equations for the evolution of the droplet's base radius and specify regimes at which different dissipation channels dominate. Our analytical predictions compare very well with experimental data.
ISSN:0743-7463
1520-5827
DOI:10.1021/la971301y