Synthesis of New Photoresponsive Polymers Containing Trifluoromethyl-Substituted Norbornadiene Moieties

Polymers containing trifluoromethyl (CF3)-substituted donor−acceptor NBD moieties in the side chain or in the main chain were synthesized by substitution or addition of a CF3−NBD−carboxylic acid derivative or by polycondensation of a CF3−NBD−dicarboxylic acid derivative. The photoisomerization of th...

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Published in:Macromolecules 2003-03, Vol.36 (6), p.1786-1792
Main Authors: Nagai, Takabumi, Shimada, Miwa, Ono, Yoshitomo, Nishikubo, Tadatomi
Format: Article
Language:English
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
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cited_by cdi_FETCH-LOGICAL-a391t-6d1a4d5ac13726b1ebc69c05469fb1fd320c2d2f24dd01144acbc54d30ca384a3
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creator Nagai, Takabumi
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Ono, Yoshitomo
Nishikubo, Tadatomi
description Polymers containing trifluoromethyl (CF3)-substituted donor−acceptor NBD moieties in the side chain or in the main chain were synthesized by substitution or addition of a CF3−NBD−carboxylic acid derivative or by polycondensation of a CF3−NBD−dicarboxylic acid derivative. The photoisomerization of the NBD moieties in these polymers proceeded very smoothly to give the corresponding QC moieties. Furthermore, the NBD moieties exhibited efficient fatigue resistance.
doi_str_mv 10.1021/ma0214207
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Synthesis of New Photoresponsive Polymers Containing Trifluoromethyl-Substituted Norbornadiene Moieties
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