Combinatorial Mapping of the Phase Behavior of ABC Triblock Terpolymers in Thin Films:  Experiments

We report on the thin film phase behavior of poly(styrene)-block-poly(2-vinylpyridine)-block-poly(tert-butyl methacrylate) triblock terpolymers with volume fractions φPS:φP2VP:φPtBMA scaling as 1:1.2:x, with x ranging from 3.05 to 4. On controlled annealing in the vapor of a nearly nonselective solv...

Full description

Saved in:
Bibliographic Details
Published in:Macromolecules 2005-03, Vol.38 (5), p.1850-1858
Main Authors: Ludwigs, S, Schmidt, K, Stafford, C. M, Amis, E. J, Fasolka, M. J, Karim, A, Magerle, R, Krausch, G
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Structure, morphology and analysis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a355t-7bd67fe4215b39ba89a86c10eca110c6839e5d3bf7d41447368cb98cfac9c97d3
cites cdi_FETCH-LOGICAL-a355t-7bd67fe4215b39ba89a86c10eca110c6839e5d3bf7d41447368cb98cfac9c97d3
container_end_page 1858
container_issue 5
container_start_page 1850
container_title Macromolecules
container_volume 38
creator Ludwigs, S
Schmidt, K
Stafford, C. M
Amis, E. J
Fasolka, M. J
Karim, A
Magerle, R
Krausch, G
description We report on the thin film phase behavior of poly(styrene)-block-poly(2-vinylpyridine)-block-poly(tert-butyl methacrylate) triblock terpolymers with volume fractions φPS:φP2VP:φPtBMA scaling as 1:1.2:x, with x ranging from 3.05 to 4. On controlled annealing in the vapor of a nearly nonselective solvent the films form terraces of well-defined thickness with a highly ordered hexagonally perforated lamella structure. Using a gradient combinatorial technique we are able to systematically map the dependence of the morphology on the film thickness. By use of substrates with different surface energy we demonstrate that the perforated lamella is a stable phase, regardless of the chemical nature of the substrate, which makes the structure and methodology robust for application in nanotechnology.
doi_str_mv 10.1021/ma049048d
format article
fullrecord <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_ma049048d</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>a185182900</sourcerecordid><originalsourceid>FETCH-LOGICAL-a355t-7bd67fe4215b39ba89a86c10eca110c6839e5d3bf7d41447368cb98cfac9c97d3</originalsourceid><addsrcrecordid>eNptkDFPwzAQhS0EEqUw8A-8MDAE7NhOYrY2agGpCIYwRxfHIS5JHNkB0Y2Vv8kvIVURXVjuSafvnt49hM4puaIkpNctEC4JT8oDNKEiJIFImDhEE0JCHshQxsfoxPs1IZQKziZIp7YtTAeDdQYa_AB9b7oXbCs81Bo_1eA1nusa3o112-1snuLMmaKx6hVn2vW22bTaeWw6nNXjWJqm9Tffn1948dFrZ1rdDf4UHVXQeH32q1P0vFxk6V2wery9T2erAJgQQxAXZRRXmodUFEwWkEhIIkWJVkApUVHCpBYlK6q45JTzmEWJKmSiKlBSybhkU3S581XOeu90lfdjAnCbnJJ820_-18_IXuzYHryCpnLQKeP3B5GQUlK650D5fG3fXDd-8I_fD4bDcmA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Combinatorial Mapping of the Phase Behavior of ABC Triblock Terpolymers in Thin Films:  Experiments</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Ludwigs, S ; Schmidt, K ; Stafford, C. M ; Amis, E. J ; Fasolka, M. J ; Karim, A ; Magerle, R ; Krausch, G</creator><creatorcontrib>Ludwigs, S ; Schmidt, K ; Stafford, C. M ; Amis, E. J ; Fasolka, M. J ; Karim, A ; Magerle, R ; Krausch, G</creatorcontrib><description>We report on the thin film phase behavior of poly(styrene)-block-poly(2-vinylpyridine)-block-poly(tert-butyl methacrylate) triblock terpolymers with volume fractions φPS:φP2VP:φPtBMA scaling as 1:1.2:x, with x ranging from 3.05 to 4. On controlled annealing in the vapor of a nearly nonselective solvent the films form terraces of well-defined thickness with a highly ordered hexagonally perforated lamella structure. Using a gradient combinatorial technique we are able to systematically map the dependence of the morphology on the film thickness. By use of substrates with different surface energy we demonstrate that the perforated lamella is a stable phase, regardless of the chemical nature of the substrate, which makes the structure and methodology robust for application in nanotechnology.</description><identifier>ISSN: 0024-9297</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/ma049048d</identifier><identifier>CODEN: MAMOBX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Structure, morphology and analysis</subject><ispartof>Macromolecules, 2005-03, Vol.38 (5), p.1850-1858</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a355t-7bd67fe4215b39ba89a86c10eca110c6839e5d3bf7d41447368cb98cfac9c97d3</citedby><cites>FETCH-LOGICAL-a355t-7bd67fe4215b39ba89a86c10eca110c6839e5d3bf7d41447368cb98cfac9c97d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=16599911$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ludwigs, S</creatorcontrib><creatorcontrib>Schmidt, K</creatorcontrib><creatorcontrib>Stafford, C. M</creatorcontrib><creatorcontrib>Amis, E. J</creatorcontrib><creatorcontrib>Fasolka, M. J</creatorcontrib><creatorcontrib>Karim, A</creatorcontrib><creatorcontrib>Magerle, R</creatorcontrib><creatorcontrib>Krausch, G</creatorcontrib><title>Combinatorial Mapping of the Phase Behavior of ABC Triblock Terpolymers in Thin Films:  Experiments</title><title>Macromolecules</title><addtitle>Macromolecules</addtitle><description>We report on the thin film phase behavior of poly(styrene)-block-poly(2-vinylpyridine)-block-poly(tert-butyl methacrylate) triblock terpolymers with volume fractions φPS:φP2VP:φPtBMA scaling as 1:1.2:x, with x ranging from 3.05 to 4. On controlled annealing in the vapor of a nearly nonselective solvent the films form terraces of well-defined thickness with a highly ordered hexagonally perforated lamella structure. Using a gradient combinatorial technique we are able to systematically map the dependence of the morphology on the film thickness. By use of substrates with different surface energy we demonstrate that the perforated lamella is a stable phase, regardless of the chemical nature of the substrate, which makes the structure and methodology robust for application in nanotechnology.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Structure, morphology and analysis</subject><issn>0024-9297</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNptkDFPwzAQhS0EEqUw8A-8MDAE7NhOYrY2agGpCIYwRxfHIS5JHNkB0Y2Vv8kvIVURXVjuSafvnt49hM4puaIkpNctEC4JT8oDNKEiJIFImDhEE0JCHshQxsfoxPs1IZQKziZIp7YtTAeDdQYa_AB9b7oXbCs81Bo_1eA1nusa3o112-1snuLMmaKx6hVn2vW22bTaeWw6nNXjWJqm9Tffn1948dFrZ1rdDf4UHVXQeH32q1P0vFxk6V2wery9T2erAJgQQxAXZRRXmodUFEwWkEhIIkWJVkApUVHCpBYlK6q45JTzmEWJKmSiKlBSybhkU3S581XOeu90lfdjAnCbnJJ820_-18_IXuzYHryCpnLQKeP3B5GQUlK650D5fG3fXDd-8I_fD4bDcmA</recordid><startdate>20050308</startdate><enddate>20050308</enddate><creator>Ludwigs, S</creator><creator>Schmidt, K</creator><creator>Stafford, C. M</creator><creator>Amis, E. J</creator><creator>Fasolka, M. J</creator><creator>Karim, A</creator><creator>Magerle, R</creator><creator>Krausch, G</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20050308</creationdate><title>Combinatorial Mapping of the Phase Behavior of ABC Triblock Terpolymers in Thin Films:  Experiments</title><author>Ludwigs, S ; Schmidt, K ; Stafford, C. M ; Amis, E. J ; Fasolka, M. J ; Karim, A ; Magerle, R ; Krausch, G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a355t-7bd67fe4215b39ba89a86c10eca110c6839e5d3bf7d41447368cb98cfac9c97d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Structure, morphology and analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ludwigs, S</creatorcontrib><creatorcontrib>Schmidt, K</creatorcontrib><creatorcontrib>Stafford, C. M</creatorcontrib><creatorcontrib>Amis, E. J</creatorcontrib><creatorcontrib>Fasolka, M. J</creatorcontrib><creatorcontrib>Karim, A</creatorcontrib><creatorcontrib>Magerle, R</creatorcontrib><creatorcontrib>Krausch, G</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ludwigs, S</au><au>Schmidt, K</au><au>Stafford, C. M</au><au>Amis, E. J</au><au>Fasolka, M. J</au><au>Karim, A</au><au>Magerle, R</au><au>Krausch, G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Combinatorial Mapping of the Phase Behavior of ABC Triblock Terpolymers in Thin Films:  Experiments</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>2005-03-08</date><risdate>2005</risdate><volume>38</volume><issue>5</issue><spage>1850</spage><epage>1858</epage><pages>1850-1858</pages><issn>0024-9297</issn><eissn>1520-5835</eissn><coden>MAMOBX</coden><abstract>We report on the thin film phase behavior of poly(styrene)-block-poly(2-vinylpyridine)-block-poly(tert-butyl methacrylate) triblock terpolymers with volume fractions φPS:φP2VP:φPtBMA scaling as 1:1.2:x, with x ranging from 3.05 to 4. On controlled annealing in the vapor of a nearly nonselective solvent the films form terraces of well-defined thickness with a highly ordered hexagonally perforated lamella structure. Using a gradient combinatorial technique we are able to systematically map the dependence of the morphology on the film thickness. By use of substrates with different surface energy we demonstrate that the perforated lamella is a stable phase, regardless of the chemical nature of the substrate, which makes the structure and methodology robust for application in nanotechnology.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ma049048d</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0024-9297
ispartof Macromolecules, 2005-03, Vol.38 (5), p.1850-1858
issn 0024-9297
1520-5835
language eng
recordid cdi_crossref_primary_10_1021_ma049048d
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Properties and characterization
Structure, morphology and analysis
title Combinatorial Mapping of the Phase Behavior of ABC Triblock Terpolymers in Thin Films:  Experiments
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-24T17%3A06%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Combinatorial%20Mapping%20of%20the%20Phase%20Behavior%20of%20ABC%20Triblock%20Terpolymers%20in%20Thin%20Films:%E2%80%89%20Experiments&rft.jtitle=Macromolecules&rft.au=Ludwigs,%20S&rft.date=2005-03-08&rft.volume=38&rft.issue=5&rft.spage=1850&rft.epage=1858&rft.pages=1850-1858&rft.issn=0024-9297&rft.eissn=1520-5835&rft.coden=MAMOBX&rft_id=info:doi/10.1021/ma049048d&rft_dat=%3Cacs_cross%3Ea185182900%3C/acs_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a355t-7bd67fe4215b39ba89a86c10eca110c6839e5d3bf7d41447368cb98cfac9c97d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true