Dendron-Functionalized Macromolecules:  Enhancing Core Luminescence and Tuning Carrier Injection

• Published in: Macromolecules 2004-06, Vol.37 (12), p.4387-4398
• Main Authors: Du, Pa, Zhu, Wei-Hong, Xie, Yu-Qing, Zhao, Fei, Ku, Chien-Fong, Cao, Yong, Chang, Chen-Pin, Tian, He
• Format: Article
• Language: English
• Subjects: Applied sciences; Exact sciences and technology; Organic polymers; Physicochemistry of polymers; Polymers with particular properties; Preparation, kinetics, thermodynamics, mechanism and catalysts
• ISSN: 0024-9297; 1520-5835
• DOI: 10.1021/ma049754e

A novel series of naphthalimide dendrimers has been synthesized based on a convergent and divergent combined approach. The dendrimers consist of naphthalimide-based cores, Fréchet-type poly(aryl ether) dendrons, and carbazole (CZ) or oxadiazole (OXZ) peripheral groups. The higher generation dendrimer has site-isolation effect, or the dilution effect of the dendrons. This configuration would reduce the aggregating extent or possibility of the core unit, thus resulting in a relatively small red-shift of absorption and fluorescent spectra when they form a solid film for the applications. Studies of steady-state fluorescence properties of the dendrimers show that excitation of the terminal chromophores results mainly in the core emission alone, as the donor emission is seriously quenched due to its effective Förster intramolecular energy transfer to the core. The dendrimers show enhanced luminescence properties of the core, and the enhanced luminescent efficiency is dependent on the generation number of the dendrimers. Time-resolved luminescent measurements further supported the conclusion that the contribution tendency for each peripheral donor is decreased with the increasing of the generation number, especially for the third generation. The dendron-incorporated carbazole unit can decrease the HOMO orbital energy by 0.4 eV, thus facilitating the hole-injection in electroluminescent (EL) devices. The preliminary EL results with a single-layer architecture made with the dendrimers by means of the spin-coating technique demonstrate that these dendrimers could be utilized as promising active nondoping emitters.