Water-Dispersible Carbon Black Nanocomposites Prepared by Surface-Initiated Atom Transfer Radical Polymerization in Protic Media

The synthesis of hydrophilic carbon black composites by grafting 2-(dimethylamino)ethyl methacrylate (DMAEMA) from functionalized carbon black using atom transfer radical polymerization (ATRP) is reported. The polymerizations were performed in methanol/water mixtures near ambient temperatures using...

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Published in:Macromolecules 2006-01, Vol.39 (2), p.548-556
Main Authors: Liu, Tianqi, Jia, Shijun, Kowalewski, Tomasz, Matyjaszewski, Krzysztof, Casado-Portilla, Rosa, Belmont, James
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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cited_by cdi_FETCH-LOGICAL-a355t-2cd28af1861ba681368049cfebd79857c997d2aacd21ca3cfd56eb3c629df8953
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container_title Macromolecules
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creator Liu, Tianqi
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description The synthesis of hydrophilic carbon black composites by grafting 2-(dimethylamino)ethyl methacrylate (DMAEMA) from functionalized carbon black using atom transfer radical polymerization (ATRP) is reported. The polymerizations were performed in methanol/water mixtures near ambient temperatures using CuBr/CuBr2/2,2‘-bipyridine as the catalytic system. Under acidic conditions or upon quaternization with ethyl bromide, the polymer-bound carbon black can form stable dispersions in water. TGA, light scattering, and AFM were used to characterize the polymer bound carbon black. 2-Hydroxyethyl methacrylate (HEMA) was random and block copolymerized with DMAEMA to form functional carbon black nanocomposites.
doi_str_mv 10.1021/ma051659y
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Water-Dispersible Carbon Black Nanocomposites Prepared by Surface-Initiated Atom Transfer Radical Polymerization in Protic Media
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