Functional Degradable Polymers by Xanthate-Mediated Polymerization

Herein we report the first example of the controlled synthesis of linear and hyperbranched copolymers of 2-methylene-1,3-dioxepane (MDO) with functional vinyl monomers to deliver a range of functional, degradable polymers by reversible deactivation radical polymerization. The copolymerization was ab...

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Published in:Macromolecules 2014-05, Vol.47 (9), p.2847-2852
Main Authors: Hedir, Guillaume G, Bell, Craig A, Ieong, Nga Sze, Chapman, Emma, Collins, Ian R, O’Reilly, Rachel K, Dove, Andrew P
Format: Article
Language:English
Subjects:
Applied sciences
Copolymerization
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
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description Herein we report the first example of the controlled synthesis of linear and hyperbranched copolymers of 2-methylene-1,3-dioxepane (MDO) with functional vinyl monomers to deliver a range of functional, degradable polymers by reversible deactivation radical polymerization. The copolymerization was able to be tuned to vary the incorporation of degradable segments to create degradable materials with predictable molar mass, low dispersity values while also featuring side-chain functionality. The formation of nanoparticles by the addition of divinyladipate to form degradable hyperbranched copolymers was proven by DLS and TEM analyses.
doi_str_mv 10.1021/ma500428e
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Applied sciences
Copolymerization
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Functional Degradable Polymers by Xanthate-Mediated Polymerization
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