Molecular-Level Processing of Conjugated Polymers. 4. Layer-by-Layer Manipulation of Polyaniline via Hydrogen-Bonding Interactions

• Published in: Macromolecules 1997-05, Vol.30 (9), p.2717-2725
• Main Authors: Stockton, W. B, Rubner, M. F
• Format: Article
• Language: English
• Subjects: Applied sciences; Exact sciences and technology; Forms of application and semi-finished materials; Polymer industry, paints, wood; Sheets and films; Technology of polymers
• ISSN: 0024-9297; 1520-5835
• DOI: 10.1021/ma9700486

The molecular-level layer-by-layer processing of polyaniline with a variety of different nonionic water soluble polymers has been demonstrated. This new type of layer-by-layer adsorption process is driven by hydrogen-bonding interactions and has been accomplished with poly(vinylpyrrolidone), poly(vinyl alcohol), poly(acrylamide), and poly(ethylene oxide). FTIR spectroscopy measurements confirm a high level of hydrogen bonding between polyaniline and the nonionic polymer in the multilayer films. The effects of solution pH and polymer molecular weight on the deposition process were investigated. Comparisons with polyaniline films assembled via an electrostatic mechanism with sulfonated polystyrene indicate that the nonionic polymers adsorb onto polyaniline with a greater density of loops and tails and form highly interpenetrated bilayers with a high polyaniline content. The conductivities of these self-assembled multilayer films were found to be on the order of 1−4 S/cm for films doped with methane sulfonic acid. It was also demonstrated that the deposition process could be carried out with mixed solutions of polyaniline and a nonionic polymer.