Synthesis of Poly(sodium styrenesulfonate-block-vinylnaphthalene) by Nitroxide-Mediated Free Radical Polymerization

The new block amphiphilic copolymer, poly(sodium styrenesulfonate-block-vinylnaphthalene) (PSSS-block-VN), was synthesized by nitroxide-mediated “living” radical polymerization in homogeneous solution. The composition of the copolymer was determined by 1H NMR spectroscopy and elemental analysis. On...

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Published in:Macromolecules 2000-10, Vol.33 (20), p.7345-7348
Main Authors: Nowakowska, Maria, Zapotoczny, Szczepan, Karewicz, Anna
Format: Article
Language:English
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Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
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cited_by cdi_FETCH-LOGICAL-a390t-5e0880004843cb866dd0a18781a469864017ddfd52b7c894a03165a7523ecf183
cites cdi_FETCH-LOGICAL-a390t-5e0880004843cb866dd0a18781a469864017ddfd52b7c894a03165a7523ecf183
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creator Nowakowska, Maria
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description The new block amphiphilic copolymer, poly(sodium styrenesulfonate-block-vinylnaphthalene) (PSSS-block-VN), was synthesized by nitroxide-mediated “living” radical polymerization in homogeneous solution. The composition of the copolymer was determined by 1H NMR spectroscopy and elemental analysis. On the basis of GPC, viscometric, and spectroscopic measurements, we proposed that the copolymer adopts a highly compressed, pseudomicellar conformation in aqueous solution.
doi_str_mv 10.1021/ma991817j
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subjects Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymers with particular properties
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Synthesis of Poly(sodium styrenesulfonate-block-vinylnaphthalene) by Nitroxide-Mediated Free Radical Polymerization
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