Single Silver Nanoparticles as Real-Time Optical Sensors with Zeptomole Sensitivity

This work utilizes dark-field optical microscopy to demonstrate the localized surface plasmon resonance λmax response of individual Ag nanoparticles to the formation of a monolayer of small-molecule adsorbates. The adsorption of fewer than 60 000 1-hexadecanethiol molecules on single Ag nanoparticle...

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Bibliographic Details
Published in:Nano letters 2003-08, Vol.3 (8), p.1057-1062
Main Authors: McFarland, Adam D, Van Duyne, Richard P
Format: Article
Language:English
Subjects:
Exact sciences and technology
General equipment and techniques
Instruments, apparatus, components and techniques common to several branches of physics and astronomy
Physics
Sensors (chemical, optical, electrical, movement, gas, etc.)
remote sensing
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Summary:This work utilizes dark-field optical microscopy to demonstrate the localized surface plasmon resonance λmax response of individual Ag nanoparticles to the formation of a monolayer of small-molecule adsorbates. The adsorption of fewer than 60 000 1-hexadecanethiol molecules on single Ag nanoparticles results in a localized surface plasmon resonance shift of 40.7 nm. Additionally, the kinetics of the single nanoparticle response was shown to be comparable to that of other real-time sensor technologies.
ISSN:1530-6984
1530-6992
DOI:10.1021/nl034372s