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Four New Triterpene Glycosides from Schefflera bodinieri Roots

Four novel triterpene glycosides named bodinitins A (1), B (2), C (3), and D (4) were isolated from the roots of Schefflera bodinieri. Based on spectroscopic data, especially 1H−H COSY and 13C−1H COSY NMR, the structures of the glycosides have been determined as 28-O-[α-l-rhamopyranosyl-(1→4)-O-β-d-...

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Bibliographic Details
Published in:Journal of natural products (Washington, D.C.) D.C.), 1996-11, Vol.59 (11), p.1043-1046
Main Authors: Zhu, Min, Yang, Shiling, Phillipson, J. David, Bowery, Norman G, Greengrass, Pam M, Bowen, David V
Format: Article
Language:English
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Summary:Four novel triterpene glycosides named bodinitins A (1), B (2), C (3), and D (4) were isolated from the roots of Schefflera bodinieri. Based on spectroscopic data, especially 1H−H COSY and 13C−1H COSY NMR, the structures of the glycosides have been determined as 28-O-[α-l-rhamopyranosyl-(1→4)-O-β-d-glucopyranosyl-(1→6)]-β-d-glucopyranoside of demethylisoaleuritolic acid (1), 28-O-[α-l-rhamopyranosyl(1→4)-O-β-d-glucopyranosyl(1→6)]-β-d-glucopyranoside of isoaleuritolic acid (2), 28-O-[α-l-rhamnopyranosyl(1→4)-O-β-d-glucopyranosyl(1→6)]-β-d-glucopyranoside of 3-oxo-8-demethylisoaleuritolic acid (3), and 28-O-[α-l-rhamopyranosyl(1→4)-O-β-d-glucopyranosyl(1→6)]-β-d-glucopyranoside of 3-oxoisoaleuritolic acid (4).
ISSN:0163-3864
1520-6025
DOI:10.1021/np960235h