Self-Assembly of an Amphiphilic [2]Rotaxane Incorporating a Tetrathiafulvalene Unit

The template-directed synthesis of a [2]rotaxane, in which a π-electron deficient ring componentcyclobis(paraquat-p-phenylene)is assembled around a π-electron rich asymmetric monopyrrolotetrathiafulvalene unit on the rod section of an amphiphilic dumbbell component that is terminated by a hydrophi...

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Bibliographic Details
Published in:Organic letters 2000-11, Vol.2 (23), p.3547-3550
Main Authors: Jeppesen, Jan Oskar, Perkins, Julie, Becher, Jan, Stoddart, J. Fraser
Format: Article
Language:English
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Summary:The template-directed synthesis of a [2]rotaxane, in which a π-electron deficient ring componentcyclobis(paraquat-p-phenylene)is assembled around a π-electron rich asymmetric monopyrrolotetrathiafulvalene unit on the rod section of an amphiphilic dumbbell component that is terminated by a hydrophilic dendritic stopper at one end and a hydrophobic tetraarylmethane stopper at the other end, is reported.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol006387s