X-ray Structure of a Novel Tetrachloro[1.1]silaferrocenophane. Hydrolysis−Polycondensation of Poly(ferrocenyldichlorosilane). Electrochemical Studies

The thermal ring-opening polymerization of 1,1‘ferrocenediyldichlorosilane (m1) led to the expected poly(ferrocenyldichlorosilane) (p1) and the new dimer d1. The molecular structure of d1 was established by X-ray crystallography, and the electrochemical behavior was indicative of an electronic inter...

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Bibliographic Details
Published in:Organometallics 2001-10, Vol.20 (20), p.4211-4215
Main Authors: Calleja, Gérard, Carré, Francis, Cerveau, Geneviève, Labbé, Pierre, Coche-Guérente, Liliane
Format: Article
Language:English
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Summary:The thermal ring-opening polymerization of 1,1‘ferrocenediyldichlorosilane (m1) led to the expected poly(ferrocenyldichlorosilane) (p1) and the new dimer d1. The molecular structure of d1 was established by X-ray crystallography, and the electrochemical behavior was indicative of an electronic interaction between the ferrocene units. The hydrolytic sol−gel polycondensation of p1 led to a material in which the polymer chain was preserved during the process, as shown by the cyclic voltammetry study.
ISSN:0276-7333
1520-6041
DOI:10.1021/om000991p