Ethylene Polymerization and Ethylene/Methyl 10-Undecenoate Copolymerization Using Nickel(II) and Palladium(II) Complexes Derived from a Bulky P,O Chelating Ligand

Cationic Ni(II) and Pd(II) complexes based on the bulky P,O ligand phenacyldi-tert-butylphosphine have been shown to be active for the polymerization of ethylene and copolymerization of ethylene and methyl 10-undecenoate, a functionalized monomer.

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Bibliographic Details
Published in:Organometallics 2002-07, Vol.21 (14), p.2836-2838
Main Authors: Liu, Weijun, Malinoski, Jon M, Brookhart, Maurice
Format: Article
Language:English
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Summary:Cationic Ni(II) and Pd(II) complexes based on the bulky P,O ligand phenacyldi-tert-butylphosphine have been shown to be active for the polymerization of ethylene and copolymerization of ethylene and methyl 10-undecenoate, a functionalized monomer.
ISSN:0276-7333
1520-6041
DOI:10.1021/om0201516