Synthesis, Structure, and Reductive Elimination Reactions of the First (σ-Aryl)palladium Complex Stabilized by IPr N-Heterocyclic Carbene

The first (σ-aryl)palladium complex stabilized with one IPr N-heterocyclic carbene and one PPh3 ligand has been synthesized via a novel method, structurally characterized, and found to undergo remarkably facile C−C reductive elimination of the 2-phenylimidazolium cation via phosphine predissociation...

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Bibliographic Details
Published in:Organometallics 2003-04, Vol.22 (8), p.1591-1593
Main Authors: Marshall, William J, Grushin, Vladimir V
Format: Article
Language:English
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Summary:The first (σ-aryl)palladium complex stabilized with one IPr N-heterocyclic carbene and one PPh3 ligand has been synthesized via a novel method, structurally characterized, and found to undergo remarkably facile C−C reductive elimination of the 2-phenylimidazolium cation via phosphine predissociation.
ISSN:0276-7333
1520-6041
DOI:10.1021/om030099t