Facile Synthesis of New, Stable, Palladium-Ethyl Derivatives Containing Nitrogen-Donor Ligands

A study of the insertion reaction of ethylene into the Pd−C bond on complexes of general formula [Pd(CH3)(N−N)2][OTf] and [Pd(CH3)(phen)(L)][OTf] led to the development of a facile procedure for the synthesis of new, stable, Pd-ethyl derivatives. The rate of this insertion reaction is affected by th...

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Bibliographic Details
Published in:Organometallics 2004-04, Vol.23 (9), p.1974-1977
Main Authors: Milani, Barbara, Marson, Angelica, Scarel, Alessandro, Mestroni, Giovanni, Ernsting, Jan Meine, Elsevier, Cornelis J
Format: Article
Language:English
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Summary:A study of the insertion reaction of ethylene into the Pd−C bond on complexes of general formula [Pd(CH3)(N−N)2][OTf] and [Pd(CH3)(phen)(L)][OTf] led to the development of a facile procedure for the synthesis of new, stable, Pd-ethyl derivatives. The rate of this insertion reaction is affected by the nature of the nitrogen-donor ligand, N−N or L.
ISSN:0276-7333
1520-6041
DOI:10.1021/om030517u