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Diphosphine Complexes of Nickel(II) Are Efficient Catalysts for the Polymerization and Oligomerization of Ethylene:  Steric Activation and Ligand Backbone Effects

Nickel(II) complexes of ligands of the type Ar2PCH2PAr2 and 1,2-Ar2PC6H4PAr2 (Ar = ortho-substituted phenyl) are active catalysts for polymerization and oligomerization of ethylene.

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Bibliographic Details
Published in:Organometallics 2004-12, Vol.23 (26), p.6077-6079
Main Authors: Dennett, James N. L, Gillon, Amy L, Heslop, Katie, Hyett, David J, Fleming, James S, Lloyd-Jones, C. Emma, Orpen, A. Guy, Pringle, Paul G, Wass, Duncan F, Scutt, James N, Weatherhead, Richard H
Format: Article
Language:English
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Summary:Nickel(II) complexes of ligands of the type Ar2PCH2PAr2 and 1,2-Ar2PC6H4PAr2 (Ar = ortho-substituted phenyl) are active catalysts for polymerization and oligomerization of ethylene.
ISSN:0276-7333
1520-6041
DOI:10.1021/om0494014