Iridabenzenes from Iridacyclopentadienes:  Unusual C−C Bond Formation between Unsaturated Hydrocarbyl Ligands

Iridabenzenes are produced by an unusual C−C coupling between the α-carbon of the alkynyl ligand and the δ-carbon of the neighboring 1,3-butadienyl ligand upon protonation of the β-carbon of the alkynyl ligand.

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Bibliographic Details
Published in:Organometallics 2005-09, Vol.24 (20), p.4849-4852
Main Authors: Chin, Chong Shik, Lee, Hyungeui, Eum, Min-Sik
Format: Article
Language:English
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Description
Summary:Iridabenzenes are produced by an unusual C−C coupling between the α-carbon of the alkynyl ligand and the δ-carbon of the neighboring 1,3-butadienyl ligand upon protonation of the β-carbon of the alkynyl ligand.
ISSN:0276-7333
1520-6041
DOI:10.1021/om050529a