Bimetallic Intermediates in the Formation of Nucleophilic Allenylzincs from Allenylpalladiums:  A DFT Study

According to DFT calculations, allenyl transfer from Pd to Zn may take place through intermediate bimetallic Pd−Zn complexes and be facilitated by the intermetallic link. The resulting bimetallic allenylzinc species display typical nucleophilic behavior in carbonyl addition reactions.

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Bibliographic Details
Published in:Organometallics 2007-05, Vol.26 (11), p.2799-2802
Main Authors: Álvarez, Rosana, de Lera, Angel R, Aurrecoechea, José M, Durana, Aritz
Format: Article
Language:English
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Summary:According to DFT calculations, allenyl transfer from Pd to Zn may take place through intermediate bimetallic Pd−Zn complexes and be facilitated by the intermetallic link. The resulting bimetallic allenylzinc species display typical nucleophilic behavior in carbonyl addition reactions.
ISSN:0276-7333
1520-6041
DOI:10.1021/om061148f