Synthesis of Platinum Acetylide Derivatives with Different Shapes and Their Gel Formation Behavior

The synthesis of a series of platinum acetylide derivatives, featuring linear, triangular, and rectangular shapes, respectively, is described. The structures of these complexes were characterized by multinuclear NMR (1H, 13C, and 31P), CSI-TOF mass spectrometry, and elemental analysis. It was found...

Full description

Saved in:
Bibliographic Details
Published in:Organometallics 2011-11, Vol.30 (21), p.5590-5594
Main Authors: Chen, Li-Jun, Zhang, Jing, He, Jiuming, Xu, Xing-Dong, Wu, Nai-Wei, Wang, De-Xian, Abliz, Zeper, Yang, Hai-Bo
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The synthesis of a series of platinum acetylide derivatives, featuring linear, triangular, and rectangular shapes, respectively, is described. The structures of these complexes were characterized by multinuclear NMR (1H, 13C, and 31P), CSI-TOF mass spectrometry, and elemental analysis. It was found that these complexes exhibited unexpectedly different gel formation properties in the most common organic solvents. Moreover, the organometallic gels of C1 and C2 exhibited concentration- and temperature-dependent emission properties.
ISSN:0276-7333
1520-6041
DOI:10.1021/om2003317