Synthesis and Self-Association of Organoplatinum(IV) Boronic Acids

Oxidative addition of ortho, meta, and para isomers of BrCH2C6H4B(OH)2 to dimethylplatinum(II) complexes gave the corresponding organoplatinum(IV) boronic acids [PtBrMe2{CH2C6H4B(OH)2}(NN)], with the bidentate ligand NN = 4,4′-bis(ethoxycarbonyl)-2,2′-bipyridine or 2,5-bis(2-pyridyl)-1,3,4-oxadiazol...

Full description

Saved in:
Bibliographic Details
Published in:Organometallics 2012-04, Vol.31 (7), p.2675-2681
Main Authors: Safa, Muhieddine A, Abo-Amer, Anwar, Borecki, Aneta, Cooper, Benjamin F. T, Puddephatt, Richard J
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Oxidative addition of ortho, meta, and para isomers of BrCH2C6H4B(OH)2 to dimethylplatinum(II) complexes gave the corresponding organoplatinum(IV) boronic acids [PtBrMe2{CH2C6H4B(OH)2}(NN)], with the bidentate ligand NN = 4,4′-bis(ethoxycarbonyl)-2,2′-bipyridine or 2,5-bis(2-pyridyl)-1,3,4-oxadiazole. The complexes undergo self-assembly in the solid state through hydrogen bonding to give dimers, polymers, or sheet structures.
ISSN:0276-7333
1520-6041
DOI:10.1021/om2009217