Carbene Complexes of Phosphorus(V) Fluorides by Oxidative Addition of 2,2-Difluorobis(dialkylamines) to Phosphorus(III) Halides

Carbene-stabilized complexes of substituted and unsubstituted phosphorus­(V) fluorides were obtained by oxidative addition of 2,2-difluorobis­(dialkylamines) to phosphorus­(III) halides. Octahedral and hydrolytically stable complexes were obtained in quantitative yields. All compounds were character...

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Bibliographic Details
Published in:Organometallics 2012-02, Vol.31 (4), p.1278-1280
Main Authors: Böttcher, Tobias, Shyshkov, Oleg, Bremer, Matthias, Bassil, Bassem S, Röschenthaler, Gerd-Volker
Format: Article
Language:English
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Summary:Carbene-stabilized complexes of substituted and unsubstituted phosphorus­(V) fluorides were obtained by oxidative addition of 2,2-difluorobis­(dialkylamines) to phosphorus­(III) halides. Octahedral and hydrolytically stable complexes were obtained in quantitative yields. All compounds were characterized in the solid state by single-crystal X-ray diffraction.
ISSN:0276-7333
1520-6041
DOI:10.1021/om2009827