Strained ansa Half-Sandwich Complexes of Ruthenium and Osmium and a Non-Iron Metallopolymer by Ring-Opening Polymerization

Herein we report the first non-iron polymer obtained from an ansa half-sandwich complex. This polymeric organometallic material was obtained from a new disilanediyl-bridged ruthenium complex upon thermally induced ring-opening polymerization (ROP). Additionally, a corresponding distannanediyl-bridge...

Full description

Saved in:
Bibliographic Details
Published in:Organometallics 2014-04, Vol.33 (7), p.1536-1539
Main Authors: Braunschweig, Holger, Dellermann, Theresa, Dewhurst, Rian D, Mies, Jan, Radacki, Krzysztof, Stellwag-Konertz, Sascha, Vargas, Alfredo
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Herein we report the first non-iron polymer obtained from an ansa half-sandwich complex. This polymeric organometallic material was obtained from a new disilanediyl-bridged ruthenium complex upon thermally induced ring-opening polymerization (ROP). Additionally, a corresponding distannanediyl-bridged osmium species is reported, the first example of an ansa half-sandwich complex of this element.
ISSN:0276-7333
1520-6041
DOI:10.1021/om500111r