Strained ansa Half-Sandwich Complexes of Ruthenium and Osmium and a Non-Iron Metallopolymer by Ring-Opening Polymerization

Herein we report the first non-iron polymer obtained from an ansa half-sandwich complex. This polymeric organometallic material was obtained from a new disilanediyl-bridged ruthenium complex upon thermally induced ring-opening polymerization (ROP). Additionally, a corresponding distannanediyl-bridge...

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Published in:Organometallics 2014-04, Vol.33 (7), p.1536-1539
Main Authors: Braunschweig, Holger, Dellermann, Theresa, Dewhurst, Rian D, Mies, Jan, Radacki, Krzysztof, Stellwag-Konertz, Sascha, Vargas, Alfredo
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cited_by cdi_FETCH-LOGICAL-a259t-4c3265b90af267d42ff17f3ec0512ad123410eae7d18f0c277faa7d3c1d521943
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container_end_page 1539
container_issue 7
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container_title Organometallics
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creator Braunschweig, Holger
Dellermann, Theresa
Dewhurst, Rian D
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Vargas, Alfredo
description Herein we report the first non-iron polymer obtained from an ansa half-sandwich complex. This polymeric organometallic material was obtained from a new disilanediyl-bridged ruthenium complex upon thermally induced ring-opening polymerization (ROP). Additionally, a corresponding distannanediyl-bridged osmium species is reported, the first example of an ansa half-sandwich complex of this element.
doi_str_mv 10.1021/om500111r
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title Strained ansa Half-Sandwich Complexes of Ruthenium and Osmium and a Non-Iron Metallopolymer by Ring-Opening Polymerization
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