Formation of C–X Bonds through Stable Low-Electron-Count Cationic Platinum(IV) Alkyl Complexes Stabilized by N‑Heterocyclic Carbenes

Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully characterized. Related species have been postulated as key intermediates in carbon–heteroatom coupling reactions and most particularly in Shilov-type chemistry. The alkyl groups e...

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Bibliographic Details
Published in:Organometallics 2014-11, Vol.33 (21), p.5944-5947
Main Authors: Rivada-Wheelaghan, Orestes, Roselló-Merino, Marta, Díez, Josefina, Maya, Celia, López-Serrano, Joaquín, Conejero, Salvador
Format: Article
Language:English
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Summary:Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully characterized. Related species have been postulated as key intermediates in carbon–heteroatom coupling reactions and most particularly in Shilov-type chemistry. The alkyl groups exhibit a pronounced electrophilic character and can undergo nucleophilic addition of pyridine, bromide, or iodide to form new carbon–heteroatom bonds. Nevertheless, direct reductive coupling to form C–X bonds can be operative in the absence of an external nucleophile source.
ISSN:0276-7333
1520-6041
DOI:10.1021/om500881k